Glenium 51
GLENIUM 51 is a new generation superplasticising
admixture based on chains of modified polycarboxylate
ether. It is primarily developed to achieve high early
strengths for the precast concrete industry where the
highest durability and performance is required.
GLENIUM 51 is compatible with all Portland cements
meeting recognised international standards and is free
from chlorides and has been formulated to comply with
ASTM C494 for Types A and F admixtures.
GLENIUM 51 is differentiated from conventional
superplasticisers in that it is based on a unique
polycarboxylate ether polymer with long lateral chains.
Conventional superplasticisers, such as those based on
sulphonated melamine and napthalene formaldehyde
condensates, at the time of mixing, become absorbed
onto the surface of the cement particles. This absorption
takes place at a very early stage in the hydration process.
The sulphonic groups of the polymer chains increase the
negative charge on the surface of the cement particle and
dispersion of the cement occurs by electrostatic
repulsion.
The long lateral chains of GLENIUM 51 greatly improve
cement dispersion. At the start of the mixing process the
same electrostatic dispersion occurs as described
previously but the presence of the lateral chains, linked to
the polymer backbone, generate a stearic hindrance that
stabilises the cement particles capacity to separate and
disperse. This mechanism provides flowable concrete
with greatly reduced water demand.